Highly Efficient Sono‐Contact‐Electrocatalysis Enabled by Fine‐Scale and Ultrasonically Generated Polytetrafluoroethylene Particles

This paper employs a range of carefully controlled experiments to develop a detailed understanding of the role of the structure, crystallinity, and chemical composition of polytetrafluoroethylene (PTFE) in driving catalytic reactions during sonication. The new findings demonstrate the significantly enhanced production of hydrogen, hydrogen peroxide, carbon monoxide, and nitrate from water, CO2, and nitrogen in the presence of PTFE during the application of ultrasound. The critical role of PTFE in the degradation of Rhodamine B and para‐nitrophenol, which are important examples of synthetic dyes and nitroaromatic compounds, respectively is demonstrated. By understanding the mechanism and optimization of the catalytic conditions, the system achieves the highest hydrogen production yield reported to date among tribocatalytic, contact‐electrocatalytic, and piezocatalytic systems, where fine‐scale PTFE particles formed during ultrasound contribute to the enhanced activity. Importantly, the impact of PTFE's physical and chemical properties, including hydrophobicity, crystallinity, and atomic composition, on its catalytic performance is investigated. The underlying mechanism of sono‐contact‐electrocatalysis is outlined by examining reactive species generated under various gas environments. These findings provide new insights into the broad applicability of PTFE in redox reactions and highlight key factors influencing its catalytic behavior in aqueous systems for environmental remediation and energy conversion.