TY - JOUR
T1 - Single-step co-deposition of nanostructured tungsten oxide supported gold nanoparticles using a gold-phosphine cluster complex as the gold precursor
AU - Molkenova, A.
AU - Sarip, R.
AU - Sathasivam, S.
AU - Umek, P.
AU - Vallejos, S.
AU - Blackman, C.
AU - Hogarth, G.
AU - Sankar, G.
PY - 2014/12/9
Y1 - 2014/12/9
N2 - The use of a molecular gold organometallic cluster in chemical vapour deposition is reported, and it is utilized, together with a tungsten oxide precursor, for the single-step co-deposition of (nanostructured) tungsten oxide supported gold nanoparticles (NPs). The deposited gold-NP and tungsten oxide supported gold-NP are highly active catalysts for benzyl alcohol oxidation; both show higher activity than SiO2 supported gold-NP synthesized via a solution-phase method, and tungsten oxide supported gold-NP show excellent selectivity for conversion to benzaldehyde.
AB - The use of a molecular gold organometallic cluster in chemical vapour deposition is reported, and it is utilized, together with a tungsten oxide precursor, for the single-step co-deposition of (nanostructured) tungsten oxide supported gold nanoparticles (NPs). The deposited gold-NP and tungsten oxide supported gold-NP are highly active catalysts for benzyl alcohol oxidation; both show higher activity than SiO2 supported gold-NP synthesized via a solution-phase method, and tungsten oxide supported gold-NP show excellent selectivity for conversion to benzaldehyde.
U2 - 10.1088/1468-6996/15/6/065004
DO - 10.1088/1468-6996/15/6/065004
M3 - Article
SN - 1468-6996
JO - Science and Technology of Advanced Materials
JF - Science and Technology of Advanced Materials
M1 - 065004
ER -