Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Shiva J. Jethwa; Luis A. Román-Ramírez; Paul A. Anderson; Gary A. Leeke

doi:10.1007/s10765-023-03186-2

Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Shiva J. Jethwa, Luis A. Román-Ramírez, Paul A. Anderson, Gary A. Leeke

London South Bank University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Phase equilibrium data for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules.

Original language	English
Article number	86
Journal	International Journal of Thermophysics
Volume	44
Issue number	6
DOIs	https://doi.org/10.1007/s10765-023-03186-2 https://doi.org/10.1007/s10765-023-03186-2
Publication status	Published - 17 Apr 2023

Bibliographical note

Publisher Copyright:
© 2023, The Author(s).

Keywords

Electrolyte
Linear carbonates
Lithium-ion batteries
Peng–Robinson equation of state
Solubility
Vapor equilibrium

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

s10765-023-03186-2Final published version, 1.04 MBLicence: CC BY 4.0

Cite this

@article{683028e9233a4961bc59df41fad40270,

title = "Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide",

abstract = "Phase equilibrium data for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules.",

keywords = "Electrolyte, Linear carbonates, Lithium-ion batteries, Peng–Robinson equation of state, Solubility, Vapor equilibrium",

author = "Jethwa, {Shiva J.} and Rom{\'a}n-Ram{\'i}rez, {Luis A.} and Anderson, {Paul A.} and Leeke, {Gary A.}",

note = "Publisher Copyright: {\textcopyright} 2023, The Author(s).",

year = "2023",

month = apr,

day = "17",

doi = "10.1007/s10765-023-03186-2",

language = "English",

volume = "44",

number = "6",

}

TY - JOUR

T1 - Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

AU - Jethwa, Shiva J.

AU - Román-Ramírez, Luis A.

AU - Anderson, Paul A.

AU - Leeke, Gary A.

PY - 2023/4/17

Y1 - 2023/4/17

N2 - Phase equilibrium data for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules.

AB - Phase equilibrium data for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules.

KW - Electrolyte

KW - Linear carbonates

KW - Lithium-ion batteries

KW - Peng–Robinson equation of state

KW - Solubility

KW - Vapor equilibrium

UR - http://www.scopus.com/inward/record.url?scp=85153290355&partnerID=8YFLogxK

U2 - 10.1007/s10765-023-03186-2

DO - 10.1007/s10765-023-03186-2

M3 - Article

SN - 0195-928X

VL - 44

JO - International Journal of Thermophysics

JF - International Journal of Thermophysics

IS - 6

M1 - 86

ER -

Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Abstract

Bibliographical note

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this