Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Shiva J. Jethwa; Luis A. Román-Ramírez; Paul A. Anderson; Gary A. Leeke

doi:10.1007/s10765-023-03186-2

Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Shiva J. Jethwa, Luis A. Román-Ramírez, Paul A. Anderson, Gary A. Leeke

London South Bank University

Research output: Contribution to journal › Article › peer-review

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Abstract

Phase equilibrium data for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules.

Original language	English
Article number	86
Journal	International Journal of Thermophysics
Volume	44
Issue number	6
DOIs	https://doi.org/10.1007/s10765-023-03186-2 https://doi.org/10.1007/s10765-023-03186-2
Publication status	Published - 17 Apr 2023

Bibliographical note

Publisher Copyright:
© 2023, The Author(s).

Keywords

Electrolyte
Linear carbonates
Lithium-ion batteries
Peng–Robinson equation of state
Solubility
Vapor equilibrium

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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title = "Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide",

abstract = "Phase equilibrium data for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules.",

keywords = "Electrolyte, Linear carbonates, Lithium-ion batteries, Peng–Robinson equation of state, Solubility, Vapor equilibrium",

author = "Jethwa, \{Shiva J.\} and Rom{\'a}n-Ram{\'i}rez, \{Luis A.\} and Anderson, \{Paul A.\} and Leeke, \{Gary A.\}",

note = "Publisher Copyright: {\textcopyright} 2023, The Author(s).",

year = "2023",

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doi = "10.1007/s10765-023-03186-2",

language = "English",

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journal = "International Journal of Thermophysics",

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T1 - Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

AU - Jethwa, Shiva J.

AU - Román-Ramírez, Luis A.

AU - Anderson, Paul A.

AU - Leeke, Gary A.

PY - 2023/4/17

Y1 - 2023/4/17

N2 - Phase equilibrium data for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules.

AB - Phase equilibrium data for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules.

KW - Electrolyte

KW - Linear carbonates

KW - Lithium-ion batteries

KW - Peng–Robinson equation of state

KW - Solubility

KW - Vapor equilibrium

UR - https://www.scopus.com/pages/publications/85153290355

U2 - 10.1007/s10765-023-03186-2

DO - 10.1007/s10765-023-03186-2

M3 - Article

SN - 0195-928X

VL - 44

JO - International Journal of Thermophysics

JF - International Journal of Thermophysics

IS - 6

M1 - 86

ER -

Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Abstract

Bibliographical note

Keywords

UN SDGs

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